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Short communications
Authors:T V Eliseeva  V A Shaposhnik
Institution:(1) Voronezh State University, Universitetskaya pl. 1, 394893 Voronezh, Russia
Abstract:The transport of carbonic acid anions through an anion-exchange membrane (AEM) during electrodialysis is studied. At current densities above limiting diffusion values, fluxes of hydrocarbonates and carbonates are lower than those of strong-electrolyte anions. The reason for the decreased fluxes is the recombination of carbonic acid ions with hydrogen ions that form during irreversible dissociation of water molecules at the solution/AEM interface
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