Hirsutellone F, a dimer of antitubercular alkaloids from the seed fungus Trichoderma species BCC 7579 |
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Authors: | Isaka Masahiko Prathumpai Wai Wongsa Patcharaporn Tanticharoen Morakot |
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Affiliation: | National Center for Genetic Engineering and Biotechnology (BIOTEC), Thailand Science Park, Klong Luang, Pathumthani. isaka@biotec.or.th |
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Abstract: | [structure: see text] Hirsutellone F (7), a novel alkaloid dimer, was isolated together with known monomers, hirsutellones A (1), B (2), and C (3), from the seed fungus Trichoderma sp. BCC 7579. The structure of 7 was elucidated by spectroscopic analysis. Studies on biomimetic chemistry, using the dimer 7, suggested that compound 8 (17,1'-dehydrohirsutellone B) should be the precursor for all hirsutellones. |
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