Rapid ligand substitution reactions in ionic liquids studied by stopped-flow technique |
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| Authors: | Illner Peter Kern Simon Begel Svetlana van Eldik Rudi |
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| Institution: | Institute for Inorganic Chemistry, University of Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen, Germany. |
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| Abstract: | Detailed kinetic studies on ligand substitution reactions of M(II)(terpy)Cl](+) complexes (M = Pt, Pd; terpy = 2,2':6',2'-terpyridine) with thiourea as entering nucleophile were for the first time performed in the imidazolium based ionic liquid emim]NTf(2)] using stopped-flow techniques, opening the route to study fast reactions of transition metal complexes in ionic liquids. |
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