A concise enantioselective synthesis of (+)-decarestrictine L via proline-catalyzed sequential α-aminooxylation and Horner–Wadsworth–Emmons olefination |
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| Authors: | Varun Rawat Pandurang V Chouthaiwale Gurunath Suryavanshi Arumugam Sudalai |
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| Institution: | aChemical Engineering and Process Development Division, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, Maharashtra, India |
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| Abstract: | A short enantioselective synthesis of (+)-decarestrictine L, a cholesterol biosynthesis inhibitor metabolite, is described using a d-proline catalyzed sequential α-aminooxylation and a Horner–Wadsworth–Emmons olefination. |
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