Highly active and stereoselective zirconium and hafnium alkoxide initiators for solvent-free ring-opening polymerization of rac-lactide |
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| Authors: | Chmura Amanda J Davidson Matthew G Frankis Catherine J Jones Matthew D Lunn Matthew D |
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| Affiliation: | Department of Chemistry, University of Bath, Claverton Down, Bath, UK. |
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| Abstract: | Under solvent-free conditions (at 130 degrees C), zirconium and hafnium amine tris(phenolate) alkoxides are extremely active, well-controlled, single-site initiators for the ring-opening polymerization of rac-lactide, yielding highly heterotactic polylactide. |
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