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A study of molecular mobility and relaxation properties of epoxy-allyl polymers during formation of interpenetrating polymer networks under conditions of the phase separation of the networks
Authors:V F Stroganov  I V Stroganov
Institution:1. Kazan State Architecture and Construction University, Zelenaya ul. 1, Kazan, Tatarstan, 420043, Russia
2. Kazan National Research Technological University, ul. Karla Marksa 68, Kazan, Tatarstan, 420015, Russia
Abstract:Molecular mobility and relaxation properties of epoxy-allyl polymers (EAPs) and features of the formation of interpenetrating polymer networks under conditions of the phase separation of the network have been studied. The presence of the extensive interphase zone between the individual epoxy and allyl component networks has been established. The segregation degree has been calculated taking into account the volume fractions of the components of the polymer mixture. The interrelation between the features of the structure of the obtained EAP with a high level of adhesion and deformation-strength characteristics of polymers in glassy and highly elastic states has been demonstrated.
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