The study of self-assembled films of triazole on iron electrodes using electrochemical methods,XPS, SEM and molecular simulation |
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Institution: | 1. University of Sfax, Faculty of Sciences, 3000 BP, 1171 Sfax, Tunisia;2. N.D. Zelinsky Institute of Organic Chemistry RAS, 119991 Moscow, Russia;3. UMR 6226 ISCR, University of Rennes I, 35042 Rennes, France |
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Abstract: | 3-Alkyl-4-amino-5-mercapto-1,2,4-triazole (AAMT) has been evaluated as corrosion inhibition for iron in 0.1 M H2SO4 when the films of AAMT were self-assembled on the surface of iron. The films of AAMT inhibitor were characterized by electrochemical impedance spectroscopy, electrochemical polarization curves Results revealed that AAMT performed excellently as a corrosion inhibitor for iron in H2SO4 solution. Surface analysis was carried out using X-ray photoelectron spectroscopy and scanning electron microscope. The mechanism of adsorption was discussed using molecular simulation. |
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