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Double template electrosynthesis of ZnO nanodot array
Institution:1. Department of Applied Chemistry, Konkuk University, Chungju Campus, Chungbuk 380-701, Republic of Korea;2. Department of Chemistry and Biochemistry and Center for Renewable Energy Science and Technology (CREST), The University of Texas at Arlington, Arlington, TX 76019-0065, USA;1. Key Laboratory of Polar Materials and Devices, Ministry of Education, and Department of Electronic Engineering, East China Normal University, 500 Dongchuan Road, Minhang District, Shanghai, 200241, China;2. Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China;1. Key Laboratory of Sensor Analysis of Tumor Marker of Education Ministry, Shandong Provincial Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;2. Qingdao Technological University (Cooperative Innovation Center of Engineering Construction and Safety in Shandong Blue Economic Zone), Qingdao 266033, China;3. Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China;1. Chemistry Department, University of Cukurova, 01330 Adana, Turkey;2. Department of Physics, Faculty Science and Letters, Adiyaman University, 02040 Adiyaman, Turkey;3. Physics Department, University of Cukurova, 01330 Adana, Turkey;4. Department of Energy Systems Engineering Tarsus Technology Faculty, Mersin University, 33400 Tarsus, Turkey;1. Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600 Dübendorf, Switzerland;2. Institut für Werkstoffe, Technical University of Braunschweig, Langer Kamp 8, 38106 Braunschweig, Germany;3. Department of Engineering Physics, Faculty of Engineering, Ankara University, 06100 Besevler, Ankara, Turkey;4. Nuclear Physics Institute (NPI), 25068 ?e?, Czech Republic;5. Technische Universität München, Forschungs-Neutronenquelle Heinz Maier-Leibnitz (MLZ), 85747 Garching, Germany;6. Steinmann Institut, Poppelsdorfer Schloss, 53115 Bonn, Germany;1. Frontier Research Institute for Interdisciplinary Sciences (FRIS), Tohoku University, Sendai 980-8578, Japan;2. Research Institute for Electromagnetic Materials, DENJIKEN, Sendai 982-0827, Japan;3. University of Toyama, Takaoka 933-8588, Japan
Abstract:This communication describes the preparation of highly-ordered nanodot arrays of ZnO, a technologically important material, by the double template approach developed by Bartlett and co-workers. Colloidal polystyrene spheres were used as the primary template, and electrodeposited polypyrrole was used as the secondary template in this study. The ZnO nanodot arrays were prepared on a polycrystalline Au substrate by electrodeposition using the pyrrole secondary template after making it insulating by potentiodynamically deactivating it. The ZnO nanodot array was characterized by scanning electron microscopy, energy-dispersive X-ray analyses, and laser Raman spectroscopy.
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