| Stereospecific hydrohalogenation reactions of electron-deficient alkynes |
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| 作者姓名： | 陆熙炎 麻生明 |
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| 作者单位： | Laboratory of Organometallic Chemistry，Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China，Laboratory of Organometallic Chemistry，Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China (No. 9288012-01)，Chinese Academy of Sciences |
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| 摘 要： | Stereospecific hydrohalogenation reactions of electron-deficient alkynes,i.e.,2-alkynoic acids,2-alkynoates,2-propynamides,2-propynenitrile,1-alkynyl phosphonates/phosphine oxides,1-alkynyl sulfoxides/triflones,and 1-alkynyl iodonium salts with lithium or sodium halides to afford Z-alkenyl derivatives and their applications in synthesis of important intermediates as well as natural products were reviewed.
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Stereospecific hydrohalogenation reactions of electron-deficient alkynes |
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| LU,Xi-Yan MA,Sheng-MingLaboratory of Organometallic Chemistry.Stereospecific hydrohalogenation reactions of electron-deficient alkynes[J].Chinese Journal of Chemistry,1998,16(5):388-396. |
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| Authors: | LU Xi-Yan MA Sheng-MingLaboratory of Organometallic Chemistry |
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| Institution: | LU,Xi-Yan MA,Sheng-MingLaboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China |
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| Abstract: | Stereospecific hydrohalogenation reactions of electron-deficient alkynes,i.e.,2-alkynoic acids,2-alkynoates,2-propynamides,2-propynenitrile,1-alkynyl phosphonates/phosphine oxides,1-alkynyl sulfoxides/triflones,and 1-alkynyl iodonium salts with lithium or sodium halides to afford Z-alkenyl derivatives and their applications in synthesis of important intermediates as well as natural products were reviewed. |
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| Keywords: | Hydrohalogenation stereospecific synthetic applications |
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