Electrochemical thiocyanation of dodecahydro-7,8-dicarba-<Emphasis Type="Italic">nido</Emphasis>-undecaborate and 7,8-dimethyldecahydro-7,8-dicarba-<Emphasis Type="Italic">nido</Emphasis>-undecaborate monoanions |
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| Authors: | D A Rudakov V L Shirokii V I Potkin N A Maier V I Bragin P V Petrovskii I B Sivaev V I Bregadze A V Kisin |
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| Institution: | (1) Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, 13 ul. Surganova, 220072 Minsk, Belarus;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation;(3) State Research Institute of Chemistry and Technology of Organoelement Compounds, 38 sh. Entuziastov, 111123 Moscow, Russian Federation |
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| Abstract: | Electrochemical thiocyanation of the dodecahydro-7,8-dicarba-nido-undecaborate and 7,8-dimethyldecahydro-7,8-dicarba-nido-undecaborate monoanions afforded thiocyanate derivatives of these compounds, which were isolated as alkylammonium salts.
The structures of the synthesized compounds were determined by the data from IR, 1H and 11B NMR, and 11B-11B NMR COSY spectroscopy.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1553–1556, July, 2005. |
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| Keywords: | carboranes potassium dodecahydro-7 8-dicarba-nido-undecaborate potassium 7 8-dimethyldecahydro-7 8-dicarba-nido-undecaborate thiocyanation electrochemistry |
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