Mono- and binuclear ruthenium(II) trifluoroacetato complexes containing monodentate co-ligands |
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| Authors: | Prashanta Sarkhel Sekhar Ch Sarker Akhilesh K Gupta Raj K Poddar |
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| Institution: | (1) Department of Chemistry, North Eastern Hill University, Bijni Complex, 793003 Shillong, India |
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| Abstract: | Summary The syntheses of new dinuclear and mononuclear complexes of RuII trifluoroacetate containing monodentate co-ligands, namely Ru2( -O2CCF3)4L2] (L = py, 2-Mepy or 3-Mepy); trans-Ru(O2CCF3)2L4] (L = 2-Mepy or 3-Mepy); Ru(O2CCF3)(PPh3)4](O2CCF3) and Ru(O2CCF3)2(CO)(MPh3)3] (M = P or As), are described. The complexes have been characterized by physical and electrochemical studies. |
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