Investigation of surface entropy for liquid less simple metals |
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Authors: | R C Gosh A Z Ziauddin Ahmed G M Bhuiyan |
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Institution: | (1) Department of Physics, University of Dhaka, 1000 Dhaka, Bangladesh |
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Abstract: | We have derived an efficient expression in closed form for the surface
entropy of liquid metals from the statistical mechanical theory of zeroth order involving hard
sphere model interaction. Using this expression we have investigated the surface entropy for liquid less simple metals namely
Zn, Cd, In, Sn, Pb, Sb, Tl and Bi selfconsistently.
The effective hard sphere diameters are obtained from the thermodynamic
perturbation theory called the LWCA. The prediction of the selfconsistent
calculation improves significantly for all concerned systems except for Zn
and Cd. The underlying cause of discrepancy for Zn and Cd is also discussed. |
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Keywords: | 68 03 Cd Surface tension and related phenomena 68 35 Md Surface thermodynamics surface energies |
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