Determination of the absolute stereochemistry of Etzionin |
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| Institution: | 1. State Key Laboratory of Natural Medicines, Jiangsu Key Laboratory of Drug Discovery for Metabolic Diseases, Center of Drug Discovery, China Pharmaceutical University, Nanjing 210009, China;2. School of Chemical Sciences, The University of Auckland, 23 Symonds St., Auckland 1142, New Zealand;3. Department of Medicinal Chemistry, College of Pharmacy, University of Florida, 1345 Center Drive, Gainesville, FL 32610, USA;1. Department of Radiation Oncology, Klinikum rechts der Isar, Technische Universität München, Munich, Germany;2. Institut für Angewandte Physik und Messtechnik (LRT2), Universität der Bundeswehr München, Neubiberg, Germany;3. Department of Radiation Oncology, Ludwig-Maximilians-Universität München, Munich, Germany;1. Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China;2. State Key Laboratory of Quality Research in Chinese Medicine, Institute of Chinese Medical Sciences, University of Macau, Macao, China;3. ARNA Laboratory, University of Bordeaux, IECB, F-33000 Bordeaux, France;4. INSERM U869, IECB, F-33600 Pessac, France;5. Partner State Key Laboratory of Environmental and Biological Analysis, Hong Kong Baptist University, PR China;1. Department of Chemistry, Graduate School of Medical Science, Kyoto Prefectural University of Medicine, Kita-ku, Kyoto 603-8334, Japan;2. Department of Medicinal Chemistry, Kyoto Pharmaceutical University, Yamashina-ku, Kyoto 607-8412, Japan;3. Department of Biochemical Engineering, Graduate School of Science and Technology, Yamagata University, Yonezawa, Yamagata 992-8510, Japan;4. Department of Chemistry, Hyogo College of Medicine, Nishinomiya, Hyogo 663-8501, Japan |
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| Abstract: | The absolute configuration of Etzionin, a marine peptide-like compound isolated in 1989 from a red tunicate collected from the Red Sea has been determined by a combination of synthetic and spectroscopic procedures. Finally, its absolute stereochemistry has been established as 3S,3′R. |
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