The synthesis and use in asymmetric epoxidation of metal salen complexes derived from enantiopure trans-cyclopentane- and cyclobutane-1,2-diamine |
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| Affiliation: | 1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, China;2. Max Planck Institute for Terrestrial Microbiology & LOEWE Center for Synthetic Microbiology (SYNMIKRO), Marburg, Germany;1. Syktyvkar State University, Syktyvkar, Republic of Komi 167001, Russia;2. Institute of Chemistry of the Komi Science Center UB RAS, Syktyvkar, Republic of Komi 167982, Russia;3. Department of Crystallography, Institute of Earth Science, Saint-Petersburg State University, St. Petersburg 199034, Russia;1. Department of Radiation Oncology and Winship Cancer Institute of Emory University, Emory University, Atlanta, Georgia;2. Department of Radiology and Imaging Sciences, Emory University, Atlanta, Georgia;1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation;2. Irkutsk State University, 1 K. Marks Str., 664003 Irkutsk, Russian Federation;3. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Lavrentiev Ave., 630090 Novosibirsk, Russian Federation |
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| Abstract: | A complete synthesis of enantiopure trans-cyclopentane-1,2-diamine and trans-cyclobutane-1,2-diamine is described. These diamines have been used as components of novel chiral salen ligands whose chromium and manganese complexes were then evaluated as oxygen transfer agents in the asymmetric epoxidation of alkenes. |
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