Organometallic compounds : LXIX. Synthesis and properties of the first chiral triorganostannyl-manganese complex |
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| Authors: | Marcel Gielen Ivan Vanden Eynde |
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| Institution: | Vrije Universiteit Brussel, T.W., AOSC, Pleinlaan 2, B-1050 Brussel Belgium |
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| Abstract: | Methyl-1-naphthylphenylstannyltetracarbonyl(diphenyl-N-methyl-N-(S)-1-phenylethylaminophosphine)manganese (I) has been prepared by two different routes from racemic methyl-1-naphthylphenyltin chloride. Fractional recrystallizations yielded two diastereomeric fractions with fx205-1 = +40.3° and —71.4°, respectively, which have identical NMR and IR spectra. |
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