Homoleptic phenyl isocyanide complexes of molybdenum and tungsten: zerovalent six-coordinate versus divalent seven-coordinate |
| |
| Authors: | Douglas D Klendworth Warren W Welters Richard A Walton |
| |
| Institution: | Department of Chemistry, Purdue University, West Lafayette, Indiana 47907 U.S.A. |
| |
| Abstract: | Electrochemical and chemical oxidations of Mo(CNPh)6 and W(CNPh)6 have been shown to yield seven-coordinate M(CNPh)7]2+. These catons, stabilized as their PF6? salts, can be obtained in yields of 80%. The redox and substitution chemistry of these new complexes have been explored. A convenient synthesis of W(CNPh)6 has been devised starting from W2(dmhp)4 (dmhp is the anion of 2,4-dimethyl-6-hydroxypyrimidine). |
| |
| Keywords: | Address any correspondence to this author |
| 本文献已被 ScienceDirect 等数据库收录！ |
