The classification of trigonal bipyramidal platinum(II), rhodium(I) and iridium(I) olefin complexes |
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| Authors: | F.R. Hartley |
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| Affiliation: | Department of Chemistry and Metallurgy, The Royal Military College of Science, Shrivenham Great Britain |
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| Abstract: | It is shown that trigonal bipyramidal platinum(II), rhodium(I) and iridium(I) olefin complexes are better classified with the platinum(O) complex [Pt(PPh3)2(C2H4)] as class T olefin complexes than with the square-planar platinum(II) complexes such as [Pt(C2H4)Cl3]- which fall in class S. The underlying reasons for this are considered to be electronic rather than steric as was previously suggested. |
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