The classification of trigonal bipyramidal platinum(II), rhodium(I) and iridium(I) olefin complexes |
| |
Authors: | FR Hartley |
| |
Institution: | Department of Chemistry and Metallurgy, The Royal Military College of Science, Shrivenham Great Britain |
| |
Abstract: | It is shown that trigonal bipyramidal platinum(II), rhodium(I) and iridium(I) olefin complexes are better classified with the platinum(O) complex Pt(PPh3)2(C2H4)] as class T olefin complexes than with the square-planar platinum(II) complexes such as Pt(C2H4)Cl3]- which fall in class S. The underlying reasons for this are considered to be electronic rather than steric as was previously suggested. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|