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Impossibility of macrocyclization of resorcinol with the phenylphosphonous acid tetraethyldiamide
Authors:Yu. I. Blokhin  Yu. V. Volchenkova  K. N. Kornilov  A. V. Akilin
Affiliation:(1) Department of Bioorganic Chemistry, Leibniz Institute of Plant Biochemistry, Weinberg 3, 06120 Halle (Saale), Germany;(2) UNIFRA, Santa Maria, RS, Brasil;(3) University of Havana, Havana, Cuba;(4) University of Brasilia, Brasilia, Brasil
Abstract:On the basis of resorcinol and phenylphosphonous acid tetraethyldiamide a series of new phosphorylated compounds was prepared for the first time. It was found that on the basis of these products the target macrocycle does not form either under mild or under rigid conditions because instead of macrocyclization oligomerization takes place.
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