|
|||||
|
|
Preparation and dynamics of vibrational hot spots in polyatomics via raman scttering |
|
| Authors: | Robert L Sundberg Eric J Heller |
| Institution: | Department of chemistry, University of California at Los Angeles, Los Angeles, California 90024, USA;Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA and Department of Chemistry, University of California at Los Angeles, Los Angeles, California 90024, USA |
| Abstract: | We exploit a recent time dependent formulation of resonance Raman scattering to examine vibrational hot spot production in molecules which have dissociative excited states. The excited-state dynamics are described by a Raman wavefunction which is used to obtain the resonance Raman (RR) spectrum. The RR spectrum will contain the spectral signature of the subsequent dynamics and decay of the hot spot initial condition. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |