Sorption of strontium on Slovak bentonites |
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Authors: | M Galamboš J Kufčáková P Rajec |
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Institution: | 1.Department of Nuclear Chemistry, Faculty of Natural Sciences,Comenius University in Bratislava,Bratislava,Slovak Republic |
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Abstract: | Sorption of Sr on five Slovak bentonites of deposits has been studied with the use of batch technique. In the experiments
there have been used natural, chemically modified and irradiated samples, in three different kinds of grain size. The pH influence
on sorption of strontium on bentonites, pH change after sorption and influence of competitive ions have been studied. Distribution
ratios have been determined for bentonite–strontium solution system as a function of contact time, pH and sorbate concentration.
The data have been interpreted in term of Langmuir isotherm. The uptake of Sr has been rapid and the sorption of strontium
has increased by increasing pH. The percentage sorption has decreased with increasing metal concentrations. The pH value after
sorption for the natrificated forms of bentonite starts already in the alkaline area and moves to the higher values. For the
natural bentonites the values occur in the neutral or in the acidic area. Sorption of Sr has been suppressed by presence of
competitive cations as follows: Ba2+ > Ca2+ > Mg2+ > NH4
+ > K+ > Na+. By sorption on natrificated samples colloidal particles and pH value increase have been formed. The bentonite exposure as
a result of interaction of γ-rays has led to expansion of the specific surface, increasing of the sorption capacity and to
the change in the solubility of the clay materials. |
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