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Study on the photovoltaic property of Cu4SnS4 synthesized by mechanochemical process
Authors:Qinmiao Chen  Xiaoming Dou  Zhenqing Li  Yi Ni  Jin Chen  Fangfang Zhou  Yoshinori Yamaguchi  Songlin Zhuang
Institution:1. Engineering Research Center of Optical Instrument and System (Ministry of Education), Shanghai Key Laboratory of Modern Optics System, School of Optical-Electrical and Computer Engineering, University of Shanghai for Science and Technology, 516 Jungong Road, Shanghai 200093, People''s Republic of China;2. Department of Physics, Shanghai Jiao Tong University, 800 Dongchuan Road, Minhang District, Shanghai 200240, People''s Republic of China;3. Photonics Advanced Research Center, Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita-city, Osaka 565-0871, Japan;4. Consolidated Research Institute for Advanced Science and Medical Care, Waseda University, 513 Wasedatsurumaki-cho, Shinjuku-ku, Tokyo 162-0041, Japan
Abstract:Photovoltaic property of Cu4SnS4 (CTS) is studied by employing a superstrate solar cell structure of Mo/CTS/In2S3/TiO2/fluorine-doped tin oxide (FTO) glass for the first time. The CTS absorber layer was prepared by a combination of mechanochemical and doctor blade processes. The annealing effects on the structural, optical and electronic properties of the CTS absorber layer were investigated. The novel CTS absorber layer shows conversion efficiency as high as 2.34% under the standard AM 1.5 condition.
Keywords:Inorganic compounds  Cu4SnS4  Photovoltaic property
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