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Solvent extraction of reduced technetium from mineral acid solutions
Authors:P Rajec  V Mukulaj  J Kadrabová
Institution:(1) Department of Nuclear Chemistry, Comenius University, 816 31 Bratislava, (Czechoslovakia)
Abstract:The extraction of reduced99mTc with 5,7-dichloroxine, tributyl phosphate (TBP) and 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 (PMBP) from HCl−LiCl mixtures has been studied. A mechanism of extraction is proposed and the stability of the chlorocomplexes of technetium (V) in a hydrochloric and—lithium chlorid—perchloric acid mixture has been established using extraction data of99mTc and spectrophotometric measurements with99Tc.
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