An alpha,alpha'-dioxothione and its |
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Authors: | Adam Frohling |
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Institution: | Institut fur Organische Chemie der Universitat, Am Hubland, D-97074 Wurzburg, Germany. |
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Abstract: | In the reaction of Ninhydrin (1a)/1,2,3-indantrione (1b) with potassium thiotosylate, 1,4-oxathiin 6 is formed in up to 63% yield as the trapping product of the intermediary alpha,alpha'-dioxothione 1c with trans-cyclooctene (3a). Additionally, up to 18% of the available sulfur is transferred to olefin 3a to thiirane 3b through the intermediary oxathiirane. |
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