Enhancing the enantioselectivity of lipase in transesterification by substrate matching: an enzyme memory based approach |
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| Authors: | Lee D Choi Y K Kim M J |
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| Institution: | Department of Chemistry, Division of Molecular and Life Science, Pohang University of Science and Technology, San 31 Hyojadong, Pohang, Kyungbuk 790-784, Korea. |
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| Abstract: | The substrate matching strategy is described as a new approach for effectively enhancing the lipase enantioselectivity in organic solvent. In the lipase-catalyzed transesterifications of 3a-c, higher enantioselectivities have been achieved using 1a-c, respectively, as the structurally matched acyl donors. |
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