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Effectof the modifier ion on the properties of MgFe2O4and ZnFe2O4 pigments
Authors:Camila S. Xavier  R. A. Candeia  M. I. B. Bernardi  S. J. G. Lima  E. Longo  C. A. Paskocimas  L. E. B. Soledade  A. G. Souza  Iêda M. G. Santos
Affiliation:1.LTM, Departamentode Química/CCEN,Universidade Federal da Paraíba,Jo?o Pessoa,Brazil;2.CMDMC, Instituto de Físicade S?o Carlos,USP,S?oCarlos,Brazil;3.LSR, Departamento de Engenharia Mecanica/CT,Universidade Federal da Paraíba,Jo?oPessoa,Brazil;4.CMDMC-LIEC,Instituto de Química,UNESP,Araraquara,Brazil;5.DM/CT,UniversidadeFederal do Rio Grande do Norte,Natal,Brazil
Abstract:Magnesium and zinc ferrites have been prepared by the polymeric precursor method. The organic material decomposition was studied by thermogravimetry (TG) and differential thermal analysis (DTA). The variation of crystalline phases and particle morphology with calcination temperature were investigated using X-ray diffraction (XRD) and scanning electronic microscopy (SEM), respectively. The colors of the ferrites were evaluated using colorimetry. Magnesium ferrite crystallizes above 800°C, presenting a yellow- orange color with a reflectance peak at the 600–650 nm range, while zinc ferrite crystallizes at 600°C, with a reflectance peak between 650–700 nm, corresponding to the red-brick color.
Keywords:magnesium ferrite  Pechini  thermal analysis  zinc ferrite
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