Preparation of Allylstannanes and Distannanes Using Zinc in Liquid Ammonia |
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| Authors: | Mieczysław Mąkosza Karol Grela |
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| Institution: | Institute of Organic Chemistry, Polish Academy of Sciences , Kasprzaka 44, PL, 01-224, Warsaw, Poland |
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| Abstract: | Abstract Barbier-type reductive coupling of allylic bromides and organotin compounds can be carried out in liquid ammonia (?33°C) using commercial zinc powder. This procedure provide a new simple and environment-friendly method for the synthesis of allylstannanes and distannanes. |
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