Organomanganese (II) Reagents: V1: Organomanganous Chlorides as a New Reagent for Ketone Synthesis via Mixed or Symmetrical Anhydrides |
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| Authors: | G Cahiez A Alexakis J F Normant |
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| Institution: | Laboratoire de Chimie des Organo-Eléments , Université Pierre et Marie Curie tour 44 4 , place Jussieu, F-75230, Paris Cédex 05, France |
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| Abstract: | We have recently described an efficient preparation of ketones (or esters) from organomanganous iodides (RMnI) and acid chlorides2 (or chloro-carbonates3). The scope of this reaction is very large and RMnI is often superior to other organometallics. However, the major limitations of this reaction are2b: |
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