Clay Catalysis: Stork's Alkylation and Acylation of Cyclohexanone Without Isolation of Enamine |
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Authors: | Mohamed Hammadi Didier Villemin |
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Institution: | Ecole Nationale Supérieure d'Ingénieurs de Caen I.S.M.R.A. , Université de Caen , U.R.A. 480 CANRS, Caen Cedex, F-14050, France |
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Abstract: | Cyclohexanone and morpholine in the presence of KSF under azeotropic distillation gave 1-morpholinocyclohexene which is alkylated or acylated in situ without isolation of the enamine. The overall yield of these Stork's reactions are better or equivalent to those obtained by isolation of the enamine. |
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