Highly Selective Synthesis of Methyl 1-Phenyl-1-(9-hydro-)fullerenylacetate |
| |
| Authors: | Yu CHEN Bo-Cheng YU Rui-Fang CAI Zu-En HUANG Hong-Kun YU Hou-Ming WU |
| |
| Affiliation: | 1. Department of Chemistry , Fudan University , Shanghai, 200433, PR China;2. Shanghai Institute of Organic Chemistry. Academia Sinica , Shanghai, 200032, PR China |
| |
| Abstract: | Isomerically pure methyl 1-phenyl-1-(9-hydro-)fullerenylacetat is synthesized in 75% yield by the reaction of C60 with the carbanions of methyl phenylacetate in C6H6/THF mixed solvent under a purified N2 atmosphere at 20°C. |
| |
| Keywords: | |
|
|
