Application of Alkali Metal Hydrides of Nanometric Size in Reduction,Cyclotrimerization and Metalation |
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| Authors: | Wenming Zhang Shijian Liao Yun Xu Yiping Zhang |
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| Affiliation: | Dalian Institute of Chemical Physics, Chinese Academy of Sciences , P.O.Box 110, Dalian, 116023, P. R. China |
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| Abstract: | Abstract: Reactions of some representative organic functional compounds by the alkali metal hydrides of nanometric size have been studied. Nitrobenzene, some aldehydes, esters and organic halides are reduced with good yield and high selectivity in many cases. Nitriles are cyclotrimerized and dimethyl sulfoxide is rapidly deprotonated. |
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