Formation of 3-Hydroxyalkyl Carbamates from Carbon Dioxide,Amines and Oxetanes |
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| Authors: | Shigeru Ishii Ming Zhou Yasuhiko Yoshida Hiromichi Noguchi |
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| Institution: | Department of Applied Chemistry , Faculty of Engineering, Toyo University , Kujirai, Kawagoe, Saitama, 350-8585, Japan |
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| Abstract: | The reactions of carbon dioxide, primary or secondary aliphatic amines and oxetanes at a CO2 pressure of 40 atm at 100–120°C without any catalysts afforded new monocarbamates of 1,3-propanediols, with concomitant formation of amino alcohols from oxetanes and amines. |
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