Microwave Assisted,Highly Efficient Solid state N- and S-Alkylation |
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Authors: | Harsha G. Jaisinghani Bhushan M. Khadilkar |
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Affiliation: | University Department of Chemical Technology , University of Mumbai , Matunga, Mumbai, 400 019, India |
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Abstract: | Secondary amines and thiophenols were alkylated with alkyl and benzyl halides rapidly on alumina supported potassium carbonate under solvent-free conditions using microwaves. Equimolar amounts of the secondary amine/thiophenol and alkyl halide were used. The procedure neither required any strong base nor a PTC. Aniline was also monobenzylated with benzylchloride. Separation of the products from the reactants was very simple by using a nonpolar solvent for desorption. |
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