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Recovery of Arenes Containing Keto or Ester Groups by the Electrochemical Reduction of Their Respective Cyclopentadienyliron Complexes
Authors:Alaa S Abd-el-aziz  Adam Piórko  Andrzej S Baranski  Ronald G Sutherland
Institution:1. Department of Chemistry , University of Saskatchewan , Saskatoon, Saskatchewan, S7N OWO, Canada;2. Department of Chemistry , University of Toronto , Toronto, Ontario, M5S 1A1, Canada;3. Department of Chemistry , University of Saskatchewan , Saskatoon, Saskatchewan, S7N OWO, Canada
Abstract:Electrochemical reduction of the cyclopentadienyliron hexafluorophosphates of benzophenone, o-chlorophenyldibenzoylmethane and diethyl ethylphenylmalonate led to the liberation of arenes without reduction of keto or ester groups in over 85% yields.
Keywords:
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