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Easy Preparation of 1,3-Di-tert-Butylbenzene and Some Derivatives Thereof
Authors:Corine MD Komen  Friedrich Bickelhaupt
Institution:Scheikundig Laboratorium , Vrije Universiteit , De Boelelaan 1083, NL-1081, HV Amsterdam, The Netherlands
Abstract:1,3-Di-tert-butylbenzene (4) can conveniently be prepared from 1-bromo-3,5-di-tert-butylbenzene (2) which, in turn, is obtained from the easily available 1,3,5-tri-tert-butylbenzene (1). The use of 4 is illustrated by the preparation of the arylphosphines 6 and 7.
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