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Asymmetric Simmons-Smith Cyclopropanation Of α,β-Unsaturated Bornane-2,3-Diol Acetals |
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| Authors: | Perry T Kaye Warner E Molema |
| Institution: | Department of Chemistry , Rhodes University , Grahamstown, 6140, Republic of South Africa |
| Abstract: | Reactionofselected α, β-unsaturated aldehydes with bornane-2-exo,3-cxo-diol has afforded a series of novel, chiral acetals which, on treatment with a Simmons-Smithreagent, undergo diastereoselective(46 - 70 %d.e.) cyclopropanatioa |
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