Phase Transfer Catalysis without Solvent. Alkylation of Phenol and Derivatives |
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Authors: | A. Loupy J. Sansoulet E. Díez-Barra J. R. Carrillo |
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Affiliation: | 1. Laboratoire des Réactions Selectives sur Supports , Univ. París-Sud. , ICMO, CNRS UA 478, 91405, Orsay, France;2. Fac. Ciencias Químicas. , Univ. Castilla-La Mancha. , 13071, Ciudad Real, Spain |
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Abstract: | The alkylation of phenol, hydroquinone and p-aminophenol is performed by phase transfer catalysis without solvent. High yields of α,ω-diphenoxyalkanes, hydroquinone diethers and high selective mono O-alkylation of p-aminophenol are obtained in very mild conditions. |
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