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A Synthesis of Fused Butenoudes
Authors:Gerald L. Larson  J. Antonio Prieto  Patricia Gonzalez
Affiliation:1. Department of Chemistry , University of Puerto Rico, Rio Piedras, PR 00931 and Hüls America, Inc./Petrarch Systems , Bartram Road, Bristol, PA, 19007;2. Hüls Americ, Inc./Petrarch Systems;3. University of Puerto Rico;4. University of Puerto Rim. NIGMS-MARC Faculty Fellow 1981-1986
Abstract:It has been shown that tert-butyldimethylsilylated (Z) 2-carboethoxymethylene cycloalkanols are readily desilylated with concomitant cyclization to give the corresponding butenolides. The (E) isomers are desilylated, but not cyclized under these conditions.
Keywords:
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