A Synthesis of Fused Butenoudes |
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Authors: | Gerald L. Larson J. Antonio Prieto Patricia Gonzalez |
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Affiliation: | 1. Department of Chemistry , University of Puerto Rico, Rio Piedras, PR 00931 and Hüls America, Inc./Petrarch Systems , Bartram Road, Bristol, PA, 19007;2. Hüls Americ, Inc./Petrarch Systems;3. University of Puerto Rico;4. University of Puerto Rim. NIGMS-MARC Faculty Fellow 1981-1986 |
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Abstract: | It has been shown that tert-butyldimethylsilylated (Z) 2-carboethoxymethylene cycloalkanols are readily desilylated with concomitant cyclization to give the corresponding butenolides. The (E) isomers are desilylated, but not cyclized under these conditions. |
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