Trichloromethyl Anion Chemistry from Trimethylsilyl Trichloroacetate |
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| Authors: | Miguel A de Jesus J Antonio Prieto Luis del Valle Gerald L Larson |
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| Institution: | Department of Chemistry , University of Puerto Rico , Rio Piedras, P.R. 00931 (USA) and Petrarch Systems, Inc. A Division of the Dynamit Nobel Group, Bartram Road, Bristol, PA, 19007. |
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| Abstract: | The reaction of trimethylsilyl trichloroacetate with aldehydes and Retones in the presence of fluoride ion gives the trichloromethyl adducts. With potassium fluoride the reaction with cyclohexenone and crotonaldehyde results in clear 1,2 addition. |
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