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Scope and Stereochemistry of [2+2] Photocycloadditions Between Cyclopentenones and 1,2-Dichlorocycloalkenes |
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| Authors: | Alan B Brown Scott E McKay Daniel E Meeroff |
| Institution: | Department of Chemistry , Florida Institute of Technology , Melbourne, FL, 32901 |
| Abstract: | Cyclopentenone and dichlorocycloalkenes give 2+2] adducts whose stereochemistry (from modern NMR) is mostly cis, anti, cis; cis, syn, cis minor adducts are also found. Cophotolysis of dichlorocyclohexene and cycloheptanocyclopentenone does not give any adduct. |
| Keywords: | N‐alkyl‐1 8‐naphthalimides Sonochemistry Aqueous media Alkyl derivative Heterogeneous sonochemistry Alkyl amines |