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Synthesis and Reactivity of the New Chiral Silylphosphite Esters {(+)-O,O-Dimethyl-L-tartrate}POSiR3 (R3 = Ph3, tBuMe2, Et3)
Authors:I Frazer Pickersgill  Paul G Devitt  Terence P Kee
Institution:School of Chemistry, University of Leeds , Leeds, LS2 9JT, U.K.
Abstract:The new, chiral silylphosphite compounds (O,O-dimethyl-L-tartrato)POSiR3, (R3 = Ph3, tBuMe2, Et3) have been synthesised and their activity as asymmetric phosphonylating reagents investigated.
Keywords:
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