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Stereoselective Synthesis of Alkenyl Alcohols Using Dissolving Metal (Ca,Na) Reduction |
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| Authors: | Jingyao Zhou Guodi Lu Xin Huang Shihui Wu |
| Affiliation: | Department of Chemistry , Fudan University , Shanghai, 200433, The Peoples Republic of China |
| Abstract: | Use of the calcium-ethylenediamine and sodium-liquid ammonia reduction systems for the ring opening of dihydropyran derivatives was studied. (Z)-Alkenyl alcohols and (E)-alkenyl alcohols were stereoselectively synthesized respectively. |
| Keywords: | Chiral ammonium salt Enantioselective epoxidation Phase-transfer catalysis α,β-unsaturated ketones |