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C-3 to C-2 Carbonyl Transposition via a Vinyl Chloride in Ring-A of Steroids |
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| Authors: | Sashi Kumar John F. Templeton Talal Hasan Zeglam |
| Affiliation: | Faculty of Pharmacy , University of Manitoba , Winnipeg, Manitoba, Canada , R3T 2N2 |
| Abstract: | Transposition of a steroid C-3 ketone to the C-2 position was carried out through the 2-chloro-2-olefin. A convenient synthesis of 5α-androstan-2-on-17β-ol acetate is described. |
| Keywords: | |