Phenylselenium Trichloride,Preparation and Use as a Vinylic Chlorination Reagent |
| |
| Authors: | Nicolai Stuhr-Hansen Lars Henriksen Janos T Kodra |
| |
| Institution: | 1. Department of Chemistry , University of Copenhagen, The H. C. ?rsted Institute , Universitetsparken 5, DK-2100, Copenhagen ?, Denmark;2. Department of Chemistry , University of Copenhagen, The H. C. ?rsted Institute , Universitetsparken 5, DK-2100, Copenhagen ?, Denmark;3. Laboratory for Organic Chemistry, E.T.H. , Zurich, CH-8092, Switzerland |
| |
| Abstract: | Phenylselenium trichloride (1) is prepared from benzeneseleninic acid (2) and thionyl chloride and used to effect vinylic chlorination, viz. the conversion of 3-chloro-2-chloromethyl-1-propene (4) into 2-chloromethyl-1,3-dichloro-propene (3). |
| |
| Keywords: | |
|
|
