Faciie-Radioiododemetallation Reactions for the Convenient Preparation of Raoioiodinated Compounds |
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Authors: | Prem C. Srivastava Furn F. Knapp Jr. George W. Kabalka Sastry A. Kunda |
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Affiliation: | 1. Nuclear Medicine Group, Health and Safety Research Division, Oak Ridge National Laboratory , Oak Ridge, Tennessee, 37831;2. Chemistry Department , University of Tennessee , Knoxville, Tennessee, 37916 |
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Abstract: | Several new methods for the preparation of vinyl iodides via mercuration and thallation reactions of vinylboronic acids have been explored. Chloramine-T oxidation of alkylvinylmercury iodides or iodide treatment of alkylvinylthallium trifluoroacetate substrates, prepared from the corresponding alkylvinylboronic acid and thallic trifluoroacetate, yields the corresponding alkylvinyl iodides. These method are also efficient for the synthesis of the corresponding radioiodinated compounds. |
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