Unambiguous Mono Deuterium Labelling of Alkyl Ethyl Ketones at the α Position of the Ethyl Group by Ruthenium (III) Catalyzed Isomerization of O-Deuterated Allylic Alcohols |
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| Authors: | C Georgoulis J M Valéry G Ville |
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| Institution: | Laboratoire de Cinétique et Mécanismes de Réactions Organiques, C.N.R.S. ER 84. Université Pierre et Marie Curie , 4 Place Jussieu, 75230, PARIS CEDEX 05, FRANCE |
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| Abstract: | Ruthenium (III) tris acetylacetonate is an efficient catalyst for the isomerization of O-deuterated alkylvinyl carbinols allowing thus a facile route to the title compounds. |
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