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Acylation of Sydnones with Acetic Anhydride in the Presence of Montmorillonite K-10
Authors:Kenneth Turnbull  Jones C. George
Affiliation:Department of Chemistry , Wright State University , Dayton, Ohio, 45435
Abstract:Various 4-acetyl sydnones 2 can be prepared in good yield by reaction of the corresponding 3-arylsydnones (cf. 1) with acetic anhydride at ~ 110°C catalyzed by Montmorillonite K-10. The reaction fails where an ortho-keto moiety is present; therein sydnone ring cleavage occurs to form the corresponding indazole 3.
Keywords:
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