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A Versatile Oxidizing Agent: Tetrakis-pyridino-cobalt(II) Dichromate Py4Co(HCrO4)2 (TPCD). Oxidations of Alcohols,Halides and Amines to Their Corresponding Carbonyl Compounds
Authors:Yuefei Hu  Hongwen Hu
Affiliation:Department of Chemistry , Nanjing University , Nanjing, 210008, People's Republic of China
Abstract:The preparation of a versatile oxidizing agent tetrakis-pyridino-cobalt (II) dichromate Py4Co(HCrO4)2 (TPCD) is presented and its structure is confirmed by x-ray crystal data. Alcohols, halides and amines are oxidized smoothly to their corresponding carbonyl compounds in good yields with TPCD.
Keywords:
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