Methyl 2, 3-Dichloropropanoate as a New Domino Bisannelating Reagent |
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| Authors: | Hitoshi Sakai Hisahiro Haglwara Takashi Hoshi Toshio Suzuki Masayoshi Ando |
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| Affiliation: | 1. Graduate School of Science and Technology, Niigata University , 2-nocho, Ikarashi Niigata , 950-2181 , JAPAN;2. Faculty of Engineering, Niigata University , 2-nocho, Ikarashi Niigata , 950-2181 , JAPAN |
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| Abstract: | Kinetically generated enolate of cyclohexenone when reacted with methyl 2, 3-dichloropropanoate provided methyl tricyclo-[3. 2. 1. 02, 7]octane-l-carboxylate and its congeners via domino Michael-Michael-alkylation reaction. |
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