Stereoselective Synthesis of Versatile Intermediates for Clerodanes Total synthesis |
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Authors: | Paul-Henri Ducrot Anne-Claire Hervier Jean-Yves Lallemand |
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Affiliation: | 1. Unité de Phytopharmacie et Médiateurs Chimiques , I.N.R.A. Route de Saint-Cyr , F-78026, Cedex, France;2. Laboratoire de Synthése Organique de l'Ecole Polytechnique , F-91128, Palaiseau Cedex, France |
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Abstract: | The stereoselective synthesis of compounds 2a-d, attractive intermediates for the synthesis of clerodane diterpenes is described in 6 to 9 steps in good overall yields from commercially available racemic Wieland-Miescher ketone. |
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