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Stereoselective Synthesis of Versatile Intermediates for Clerodanes Total synthesis
Authors:Paul-Henri Ducrot  Anne-Claire Hervier  Jean-Yves Lallemand
Affiliation:1. Unité de Phytopharmacie et Médiateurs Chimiques , I.N.R.A. Route de Saint-Cyr , F-78026, Cedex, France;2. Laboratoire de Synthése Organique de l'Ecole Polytechnique , F-91128, Palaiseau Cedex, France
Abstract:The stereoselective synthesis of compounds 2a-d, attractive intermediates for the synthesis of clerodane diterpenes is described in 6 to 9 steps in good overall yields from commercially available racemic Wieland-Miescher ketone.
Keywords:
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